The hallmark of a conventional crystal such as table salt is translational symmetry. Quasicrystals do not have that symmetry and so can exhibit a wider structural variety than their more constrained brethren. But quasicrystals, like crystals, do have long-range correlations and display sharp, structure-revealing diffraction patterns. To date, more than 100 quasicrystals have been synthesized in the lab. Now Luca Bindi of the Natural History Museum of Florence has teamed up with Paul Steinhardt and colleagues from Princeton and Harvard universities to present evidence for a natural version of one of those quasicrystals: icosahedral Al63Cu24Fe13. The material, a 100-μm grain, is from a mineral assemblage (left figure) excavated from the Koryak Mountains in Russia and now housed in the Florence museum; the very complexity of the sample argues for its natural formation. In consultation with his US-based colleagues, Bindi identified the sample as possibly hosting a quasicrystal. The US team then probed a small piece of it with transmission electron microscopy. Diffraction patterns such as shown in the right figure identified quasicrystal regions; the 10-fold symmetry cannot be generated by crystals. Subsequent analysis of x rays scattered off pure quasicrystal grains determined the material’s chemical formula. Geologists and physicists have much to learn about the conditions under which quasicrystals form. The study of natural materials can help address that question and may turn up new, never-before contemplated structures. (L. Bindi et al., Science 324, 1306, 2009.) —Steven K. Blau
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